This is a very, very specific issue that I have been wrangling with since at least 2021 or so, and I doubt it's happening for anyone else, or people just don't care enough to notice, but I figured I ought to report it anyway. This occurs both with and without FBT.
Switching into any avatar in the game, calibrating my full body, and placing my arms at my side reveals that my arms are not centered about my body. Additionally, my avatar has a very slight lean to it.
Currently the problem is solvable, but it requires a trick in SteamVR to basically lie about where my hardware is physically located (OpenVR Input Emulator), adding a ~2cm right offset to my HMD.
Since this is not so easy to explain with words, I have recorded my raw VR view and demonstrated the problem and how I fix it for myself: https://youtu.be/jvfrAz4HVL8
And, since it is a very legitimate question that might come off as a bit impolite to ask, I will answer it ahead of time: I did indeed check my real physical self to make sure my spine isn't messed up or something, and I can confirm that I stand up straight as an arrow in person :P
Addendum:
I have also checked my playspace configuration. This has persisted across several different spaces as I have used different parts of my home for my VR setup. I'm using an Index with 3 Lighthouses.